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4-Bromo- and 4-chlorothymol (4-bromo-2-isopropyl-5-methylphenol and 4-chloro-2-isopropyl-5-methylphenol, respectively) pKa were satisfactorily calculated with all solvation models, and SMD was suitable for the accurate determination of the pKa of phenols with complex substituents, such as -CN and -NO 2 groups

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